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Methane partial oxidation over NiO-MgO/Ce

Piyawat PUE-ON, Vissanu MEEYOO, Thirasak RIRKSOMBOOON

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 3,   Pages 289-296 doi: 10.1007/s11705-013-1345-2

Abstract: Methane partial oxidation (MPO) is considered as an alternative method to produce hydrogen because it is an exothermic reaction to afford a suitable H /CO ratio of 2. However, carbon deposition on a catalyst is observed as a major cause of catalyst deactivation in MPO. In order to find suitable catalysts that prevent the carbon deposition, NiO-MgO/Ce Zr O (CZO) supported catalysts were prepared via the co-impregnation (C) and sequential incipient wetness impregnation (S) methods. The amount of Ni loading was fixed at 15 wt-% whereas the amount of MgO loading was varied from 5 to 15 wt-%. The results revealed that the addition of MgO shifted the light-off temperatures to higher temperatures. This is because the Ni surface was partially covered with MgO, and the strong interaction between NiO and NiMgO over CZO support led to the difficulty in reducing NiO to active Ni and thus less catalytic activity. However, among the catalysts tested, the 15Ni5Mg/CZO (S) catalyst exhibited the best catalytic stability for MPO after 18 h on stream at 750°C. Moreover, this catalyst had a better resistance to carbon deposition due to its high metallic Ni dispersion at high temperature.

Keywords： methane partial oxidation     NiO     ceria-zirconia     MgO     mixed oxide solid solution    

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Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

Frontiers in Energy doi: 10.1007/s11708-023-0901-9

Abstract: Interconnector is a critical component to construct solid oxide cells (SOCs) stack.

Keywords： interconnector coating     plasma spray     electrochemical performance     Cr diffusion inhibition     solid oxide    

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Significant potential of Solid Oxide Fuel Cell systems for distributed power generation and carbon neutrality

Frontiers in Energy 2022, Volume 16, Issue 6,   Pages 879-882 doi: 10.1007/s11708-022-0850-8

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Numerical investigation of the chemical and electrochemical characteristics of planar solid oxide fuel

Yuzhang WANG, Shilie WENG, Yiwu WENG

Frontiers in Energy 2011, Volume 5, Issue 2,   Pages 195-206 doi: 10.1007/s11708-011-0148-8

Abstract: A fully three-dimensional mathematical model of a planar solid oxide fuel cell (SOFC) with complete direct

Keywords： planar solid oxide fuel cell (SOFC)     direct internal reforming     chemical reaction     methane     electrochemical    

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Performance comparison of cocurrent and countercurrent flow solid oxide fuel cells

Huisheng ZHANG, Shilie WENG, Ming SU

Frontiers in Energy 2011, Volume 5, Issue 2,   Pages 207-213 doi: 10.1007/s11708-011-0151-0

Abstract: Solid oxide fuel cell (SOFC) is a complicated system with heat and mass transfer as well as electrochemical

Keywords： solid oxide fuel cell (SOFC)     cocurrent     countercurrent     dynamic performance    

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Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 1,   Pages 1-14 doi: 10.1007/s11705-022-2176-9

Abstract: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2–TiO2 were introduced to the polyurethane (PU) matrix. Electrochemical techniques were used to investigate the barrier properties of the synthesized PU–ATA/SiO2–TiO2 nanocomposite coated steel specimen. In natural seawater, electrochemical impedance spectroscopy experiments indicated outstanding protective behaviour for the PU–ATA/SiO2–TiO2 coated steel. The coating resistance (Rcoat) of PU–ATA/SiO2–TiO2 was determined to be 2956.90 kΩ·cm–2. The Rcoat of the PU–ATA/SiO2–TiO2 nanocomposite coating was found to be over 50% higher than the PU coating. The current measured along the scratched surface of the PU–ATA/SiO2–TiO2 coating was found to be very low (1.65 nA). The enhanced ATA/SiO2–TiO2 nanoparticles inhibited the entry of electrolytes into the coating interface, as revealed by scanning electron microscopy/energy dispersive X-ray spectroscopy and X-ray diffraction analysis of the degradation products. Water contact angle testing validated the hydrophobic nature of the PU–ATA/SiO2–TiO2 coating (θ = 115.4°). When the concentration of ATA/SiO2−TiO2 nanoparticles was 2 wt %, dynamic mechanical analysis revealed better mechanical properties. Therefore, the newly synthesised PU–ATA/SiO2–TiO2 nanocomposite provided excellent barrier and mechanical properties due to the addition of ATA/SiO2–TiO2 nanoparticles to the polyurethane, which inhibited material degradation and aided in the prolongation of the coated steel’s life.

Keywords： SiO2/TiO2 nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical techniques     corrosion     colloids and interfaces    

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Part-load, startup, and shutdown strategies of a solid oxide fuel cell-gas turbine hybrid system

Yang LI, Yiwu WENG, Shilie WENG

Frontiers in Energy 2011, Volume 5, Issue 2,   Pages 181-194 doi: 10.1007/s11708-011-0149-7

Abstract: Current work on the performance of a solid oxide fuel cell (SOFC) and gas turbine hybrid system is presented

Keywords： solid oxide fuel cell (SOFC)     hybrid system     part-load strategy     startup     shutdown    

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Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

Frontiers in Energy 2019, Volume 13, Issue 4,   Pages 770-797 doi: 10.1007/s11708-019-0651-x

Abstract: Recently, the development and fabrication of electrode component of the solid oxide fuel cell (SOFC)Impressive progress has been made in the development of alternative electrode materials with mixed conducting

Keywords： double perovskites     electrode materials     hydrocarbon fuel     solid oxide fuel cells    

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Yue’s solution of classical elasticity in

Zhong-qi Quentin YUE

Frontiers of Structural and Civil Engineering 2015, Volume 9, Issue 3,   Pages 215-249 doi: 10.1007/s11709-015-0298-6

Abstract: exact and complete fundamental singular solutions for the boundary value problem of a -layered elastic solidof either transverse isotropy or isotropy subject to body force vector at the interior of the solid.Findings of this solution formulation are further used in the companion paper for mathematical verificationsolutions have been named by other researchers as Yue’s approach, Yue’s treatment, Yue’s method and Yue’s solution

Keywords： elasticity     solution     layered solid     graded material    

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Achievements and trends of solid oxide fuel cells in clean energy field: a perspective review

Abdalla M. ABDALLA, Shahzad HOSSAIN, Pg MohdIskandr PETRA, Mostafa GHASEMI, Abul K. AZAD

Frontiers in Energy 2020, Volume 14, Issue 2,   Pages 359-382 doi: 10.1007/s11708-018-0546-2

Abstract: Solid oxide fuel cell (SOFC) is the most efficient type of the fuel cell types involved with hydrogen

Keywords： solid oxide fuel cells (SOFCs)     clean energy     design     micro-scale     nano-scale     performance    

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Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 2,   Pages 164-171 doi: 10.1007/s11783-010-0019-2

Abstract: called ultrasonic-assisted membrane reaction (UAMR) was reported for the fabrication of ceria-zirconia solidsolution.A series of ceria-zirconia solid solutions with different Ce/Zr molar ratios were prepared by the UAMRbe superior, especially when the Ce/Zr molar ratio was lower than 1, in fabricating ceria-zirconia solid

Keywords： membrane reaction     ceria-zirconia     Ce/Zr molar ratio     solid solution     hydrogen temperature-programmed reduction    

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Modelling the dynamic response of a solid oxide steam electrolyser to transient inputs during renewable

Qiong CAI, Nigel P. BRANDON, Claire S. ADJIMAN,

Frontiers in Energy 2010, Volume 4, Issue 2,   Pages 211-222 doi: 10.1007/s11708-010-0037-6

Abstract: Solid oxide electrolyser cells (SOEC) may provide a cost-effective and green route to hydrogen production

Keywords： hydrogen production     renewable energy     solid oxide electrolyser cell     1D dynamic model     dynamic behaviour    

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Performance assessment of a power-to-gas process based on reversible solid oxide cell

Hanaâ Er-rbib, Nouaamane Kezibri, Chakib Bouallou

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 4,   Pages 697-707 doi: 10.1007/s11705-018-1774-z

Abstract: In this work, a promising solution to this issue is investigated using one of the most emerging technologiesof electricity conversion: reversible solid oxide cells (RSOC).

Keywords： renewable electricity     storage     co-electrolysis     methanation     carbone capture    

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The development review of cathode materials for proton conducting solid oxide fuel cells

Zhao Ling,Xia Changrong

Strategic Study of CAE 2013, Volume 15, Issue 2,   Pages 88-97

Abstract: Solid oxide fuel cells (SOFCs), which have been regarded as keystone for the future energy economyProton conducting solid oxide fuel cells (H-SOFCs) have attracted much attention for their unique

Keywords： solid oxide fuel cell     proton conductor     cathode material     reaction model    

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Prospect of carbon-based solid oxide fuel cells

Han Minfang,Peng Suping

Strategic Study of CAE 2013, Volume 15, Issue 2,   Pages 4-6

Abstract: In all kinds of fuel cells, solid oxide fuel cell (SOFC) could use many kinds of carbon-based fuelsAll solid structures are adopted in SOFC system and excellent long term stability is observed during

Keywords： solid oxide fuel cell     carbon-based fuels     power generation system    

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Title Author Date Type Operation

Methane partial oxidation over NiO-MgO/Ce

Piyawat PUE-ON, Vissanu MEEYOO, Thirasak RIRKSOMBOOON

Journal Article

Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

Journal Article

Significant potential of Solid Oxide Fuel Cell systems for distributed power generation and carbon neutrality

Journal Article

Numerical investigation of the chemical and electrochemical characteristics of planar solid oxide fuel

Yuzhang WANG, Shilie WENG, Yiwu WENG

Journal Article

Performance comparison of cocurrent and countercurrent flow solid oxide fuel cells

Huisheng ZHANG, Shilie WENG, Ming SU

Journal Article

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

Journal Article

Part-load, startup, and shutdown strategies of a solid oxide fuel cell-gas turbine hybrid system

Yang LI, Yiwu WENG, Shilie WENG

Journal Article

Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

Journal Article

Yue’s solution of classical elasticity in

Zhong-qi Quentin YUE

Journal Article

Achievements and trends of solid oxide fuel cells in clean energy field: a perspective review

Abdalla M. ABDALLA, Shahzad HOSSAIN, Pg MohdIskandr PETRA, Mostafa GHASEMI, Abul K. AZAD

Journal Article

Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

Journal Article

Modelling the dynamic response of a solid oxide steam electrolyser to transient inputs during renewable

Qiong CAI, Nigel P. BRANDON, Claire S. ADJIMAN,

Journal Article

Performance assessment of a power-to-gas process based on reversible solid oxide cell

Hanaâ Er-rbib, Nouaamane Kezibri, Chakib Bouallou

Journal Article

The development review of cathode materials for proton conducting solid oxide fuel cells

Zhao Ling,Xia Changrong

Journal Article

Prospect of carbon-based solid oxide fuel cells

Han Minfang,Peng Suping

Journal Article